In getting ready to own horses again, I've done some research. Since every area is different, I would contact your local co-op extention office to see what they suggest for your area. Meaning what is good to have in the South, may not be true for the North due to temps or soil, etc. Also they can tell you what could be poisonous to horses.
I found these during my research and think they have some good info.
http://www.whmentors.org/saf/poison.html
http://www.raspberryridge.com/Feature-Poisonous%20plants.htm
http://www.todayshorse.com/Articles/BeneficialInsectsForHorses.htm